Dichromate Ion · Cr₂O₇²⁻

Cr₂O₇²⁻ Lewis Structure

A bridging oxygen connects two chromium centers; representative Lewis contributors distribute Cr=O and Cr–O⁻ bonds across terminal oxygens.

Cr₂O₇²⁻
[O₃Cr—O—CrO₃]²⁻
Reviewed stored connectivity; detailed electron placement is explained below
Total valence electrons56
Reviewed connectivity[O₃Cr—O—CrO₃]²⁻
GeometryTwo tetrahedral CrO₄ units sharing one oxygen
Support levelReviewed guide

Dichromate Ion overview

The stored Lewis connectivity is [O₃Cr—O—CrO₃]²⁻. A bridging oxygen connects two chromium centers; representative Lewis contributors distribute Cr=O and Cr–O⁻ bonds across terminal oxygens.

How to draw Cr₂O₇²⁻

  1. Count 56 valence electrons. Include charge adjustments before drawing.
  2. Use the reviewed connectivity [O₃Cr—O—CrO₃]²⁻. Do not infer a different isomer from the formula alone.
  3. Place the required single, double or multiple bonds. Keep a running electron total.
  4. Complete terminal valence shells and add lone pairs or formal charges. A bridging oxygen connects two chromium centers; representative Lewis contributors distribute Cr=O and Cr–O⁻ bonds across terminal oxygens.
  5. Verify the total electron count and geometry. The reviewed geometry is Two tetrahedral CrO₄ units sharing one oxygen.

Why this example matters

A bridging oxygen connects two chromium centers; representative Lewis contributors distribute Cr=O and Cr–O⁻ bonds across terminal oxygens.

Scope and model limits

This is a transition-metal electron-bookkeeping model, not a complete metal–oxygen molecular-orbital description.

Common mistakes

  • Drawing two disconnected chromate ions
  • Omitting the bridging oxygen
  • Applying a simple main-group octet rule to chromium

Last reviewed: 2026-07-16. Educational reference only; verify graded work with course materials.