Reviewed transition-metal oxyanion guide

MnO₄⁻ Lewis Structure: Permanganate Ion

A common Lewis bookkeeping form draws three Mn=O bonds and one Mn–O⁻ bond, with four equivalent placements. This is useful for formal-charge exercises but is not a complete orbital description of Mn–O bonding.

Reviewed July 16, 2026 · Model limitation stated explicitly

Quick answer

Electron count

Mn contributes 7, four O contribute 24 and the negative charge adds 1: 32 electrons.

Geometry

Four oxygen positions around manganese give tetrahedral geometry.

Charge

In the displayed contributor, the single-bonded oxygen carries −1.

Classroom drawing method

  1. Place Mn in the center and connect four oxygens.
  2. Complete oxygen octets and maintain 32 total electrons.
  3. To minimize formal charges in the common model, use three Mn=O bonds and one Mn–O⁻ bond.
  4. Draw four equivalent contributors by moving the single bond and negative charge.
  5. Place brackets and the overall − charge around the ion.

Important limitation

Formal Lewis structures are much less complete for transition-metal compounds than for ordinary second-period covalent molecules. The displayed bond orders are electron-bookkeeping conventions and should not be read as a full molecular-orbital treatment.

Use for: electron counting, formal charge and tetrahedral VSEPR-style comparison. Do not use as: a complete explanation of Mn–O bond character.