Aniline · C₆H₇N

C₆H₇N Lewis Structure

The nitrogen lone pair conjugates with the benzene π system, reducing its availability compared with an aliphatic amine.

C₆H₇N
C₆H₅—NH₂
Reviewed stored connectivity; detailed electron placement is explained below
Total valence electrons36
Reviewed connectivityC₆H₅—NH₂
GeometryPlanar aromatic ring; nitrogen approximately planar from conjugation
Support levelReviewed guide

Aniline overview

The stored Lewis connectivity is C₆H₅—NH₂. The nitrogen lone pair conjugates with the benzene π system, reducing its availability compared with an aliphatic amine.

How to draw C₆H₇N

  1. Count 36 valence electrons. Include charge adjustments before drawing.
  2. Use the reviewed connectivity C₆H₅—NH₂. Do not infer a different isomer from the formula alone.
  3. Place the required single, double or multiple bonds. Keep a running electron total.
  4. Complete terminal valence shells and add lone pairs or formal charges. The nitrogen lone pair conjugates with the benzene π system, reducing its availability compared with an aliphatic amine.
  5. Verify the total electron count and geometry. The reviewed geometry is Planar aromatic ring; nitrogen approximately planar from conjugation.

Why this example matters

The nitrogen lone pair conjugates with the benzene π system, reducing its availability compared with an aliphatic amine.

Scope and model limits

The page shows the neutral aniline connectivity and representative resonance interaction, not a single localized-bond picture.

Common mistakes

  • Omitting the nitrogen lone pair
  • Calling nitrogen fully tetrahedral without discussing conjugation
  • Drawing an N=ring double bond as the only structure

Last reviewed: 2026-07-16. Educational reference only; verify graded work with course materials.