Hydrogen bromide · HBr

HBr Lewis Structure

HBr has one H–Br single bond and three lone pairs on bromine. The shared pair satisfies hydrogen's duet and helps bromine complete an octet.

HBr
H—Br:
Three lone pairs on bromine
Total valence electrons8
Bond order1
Bromine lone pairs3
GeometryLinear

HBr overview

The H–Br bond contains two electrons. Six more remain as three lone pairs on bromine, giving both atoms their expected valence shells.

How to draw HBr

  1. Count 8 valence electrons.
  2. Draw one H–Br single bond.
  3. Add three lone pairs to bromine.
  4. Verify a hydrogen duet, bromine octet and zero formal charges.

Molecule and aqueous acid

HBr is hydrogen bromide as a molecular compound. In water it is commonly discussed as hydrobromic acid, where ionization and solvation must be considered.

Common mistakes

  • Adding electrons around hydrogen.
  • Using an H=Br double bond.
  • Leaving off bromine lone pairs.
  • Confusing the molecule with Br⁻ alone.

Last reviewed: July 16, 2026. Educational reference only.