Sulfur trioxide · SO3 · Reviewed guide

SO3 Lewis Structure

SO₃ has 24 valence electrons and trigonal planar geometry. The generator shows the common expanded-octet form with three S=O bonds and zero formal charges, while some courses discuss charge-separated resonance contributors.

SO₃
O=S(=O)=O
Common expanded-octet representation; trigonal planar atom arrangement
Valence electrons24
Central atomSulfur
GeometryTrigonal planar
Bond angle120°

How to draw SO3

  1. Count 24 electrons.
    Sulfur contributes 6 and three oxygens contribute 18.
  2. Connect sulfur to three oxygens.
    Begin with three S–O single bonds.
  3. Complete oxygen octets.
    This creates a charge-separated octet-only contributor.
  4. Apply the convention used by your course.
    In the common expanded-octet form, oxygen lone pairs become three S=O bonds and formal charges become zero.
  5. Check the geometry.
    Three bonding domains and no sulfur lone pair give trigonal planar geometry.

Why drawings differ

Lewis structures are simplified electron-accounting models. Expanded-octet and charge-separated contributors emphasize different bookkeeping choices; neither should be interpreted as a complete quantum-mechanical bonding description.

Geometry

All three oxygen atoms occupy equivalent positions around sulfur in a plane. The ideal O–S–O angle is 120°.

Common mistakes

  • Giving sulfur a lone pair and calling SO3 trigonal pyramidal.
  • Confusing neutral SO3 with sulfate, SO4²−.
  • Using only 18 electrons.
  • Presenting one Lewis convention as a literal picture of localized bonds.

Reviewed July 16, 2026. Educational reference only; use the convention required by your course.