Oxygen molecule · O2 · Reviewed guide

O2 Lewis Structure

The standard Lewis structure is O=O with two lone pairs on each oxygen. It satisfies the 12-electron count and gives zero formal charges.

O₂
·· ·· O = O ·· ··
Two lone pairs on each oxygen
Valence electrons12
Bond orderDouble
Lone pairs4 total
Formal charges0, 0

How to draw O2

  1. Count 12 electrons.
    Each oxygen contributes 6.
  2. Connect the oxygen atoms.
    Begin with a single bond.
  3. Complete octets.
    A single bond with all remaining electrons gives an unfavorable electron arrangement.
  4. Form an O=O double bond.
    Move one lone pair into the bond.
  5. Leave two lone pairs on each oxygen.
    All 12 electrons are used and both formal charges are zero.

Electron check

The double bond contains 4 electrons and the four lone pairs contain 8, totaling 12.

Model limitation

The simple Lewis structure is useful for electron counting, but it does not explain oxygen's observed paramagnetism. Molecular orbital theory is needed for that behavior.

Common mistakes

  • Drawing only a single bond.
  • Showing three lone pairs on each oxygen after adding a double bond.
  • Using the Lewis diagram as proof that O2 is diamagnetic.

Reviewed July 16, 2026. Educational reference only.