Carbon monoxide · CO · Reviewed guide

CO Lewis Structure

The lowest-octet Lewis structure is ⁻C≡O⁺. Carbon and oxygen share a triple bond, each atom has one lone pair, and the formal charges are unusual but required.

CO
⁻:C≡O:⁺
One lone pair on each atom; C− and O+
Valence electrons10
Bond orderTriple
GeometryLinear
Formal chargesC−, O+

How to draw CO

  1. Count 10 electrons.
    Carbon contributes 4 and oxygen contributes 6.
  2. Connect C and O.
    A single bond alone cannot give both atoms octets.
  3. Form a triple bond.
    Six electrons are shared between the atoms.
  4. Add one lone pair to each atom.
    This uses the remaining four electrons.
  5. Calculate formal charges.
    Carbon is −1 and oxygen is +1; the molecule remains neutral overall.

Why the charges look reversed

Lewis formal charge is electron bookkeeping, not a direct map of partial charge. The octet-satisfying structure assigns carbon −1 and oxygen +1 even though oxygen is more electronegative.

Electron check

The triple bond contains 6 electrons and the two lone pairs contain 4, totaling 10.

Common mistakes

  • Drawing C=O with only a double bond and incomplete octets.
  • Omitting formal charges because the molecule is neutral.
  • Putting both lone pairs on oxygen.
  • Assuming formal charge and partial charge are the same concept.

Reviewed July 16, 2026. Educational reference only.